Alkynyl Ligands as Building Blocks for the Preparation of Phosphorescent Iridium(III) Emitters: Alternative Synthetic Precursors and Procedures

[Image: see text] Alkynyl ligands stabilize dimers [Ir(μ-X)(3b)(2)](2) with a cis disposition of the heterocycles of the 3b ligands, in contrast to chloride. Thus, the complexes of this class—cis-[Ir(μ(2)-η(2)-C≡CPh){κ(2)-C,N-(C(6)H(4)-Isoqui)}(2)](2) (Isoqui = isoquinoline) and cis-[Ir(μ(2)-η(2)-C≡...

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Detalles Bibliográficos
Autores principales: Adamovich, Vadim, Benítez, María, Boudreault, Pierre-Luc, Buil, María L., Esteruelas, Miguel A., Oñate, Enrique, Tsai, Jui-Yi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490848/
https://www.ncbi.nlm.nih.gov/pubmed/35438993
http://dx.doi.org/10.1021/acs.inorgchem.2c00197

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490848/
https://www.ncbi.nlm.nih.gov/pubmed/35438993
http://dx.doi.org/10.1021/acs.inorgchem.2c00197

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