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Alkynyl Ligands as Building Blocks for the Preparation of Phosphorescent Iridium(III) Emitters: Alternative Synthetic Precursors and Procedures
[Image: see text] Alkynyl ligands stabilize dimers [Ir(μ-X)(3b)(2)](2) with a cis disposition of the heterocycles of the 3b ligands, in contrast to chloride. Thus, the complexes of this class—cis-[Ir(μ(2)-η(2)-C≡CPh){κ(2)-C,N-(C(6)H(4)-Isoqui)}(2)](2) (Isoqui = isoquinoline) and cis-[Ir(μ(2)-η(2)-C≡...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490848/ https://www.ncbi.nlm.nih.gov/pubmed/35438993 http://dx.doi.org/10.1021/acs.inorgchem.2c00197 |