Introducing the Catalytic Amination of Silanes via Nitrene Insertion

[Image: see text] The direct functionalization of Si–H bonds by the nitrene insertion methodology is described. A copper(I) complex bearing a trispyrazolylborate ligand catalyzes the transfer of a nitrene group from PhI=NTs to the Si–H bond of silanes, disilanes, and siloxanes, leading to the exclus...

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Detalles Bibliográficos
Autores principales: Rodríguez, Anabel M., Pérez-Ruíz, Jorge, Molina, Francisco, Poveda, Ana, Pérez-Soto, Raúl, Maseras, Feliu, Díaz-Requejo, M. Mar, Pérez, Pedro J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490852/
https://www.ncbi.nlm.nih.gov/pubmed/35648453
http://dx.doi.org/10.1021/jacs.2c03739

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490852/
https://www.ncbi.nlm.nih.gov/pubmed/35648453
http://dx.doi.org/10.1021/jacs.2c03739

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