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Introducing the Catalytic Amination of Silanes via Nitrene Insertion
[Image: see text] The direct functionalization of Si–H bonds by the nitrene insertion methodology is described. A copper(I) complex bearing a trispyrazolylborate ligand catalyzes the transfer of a nitrene group from PhI=NTs to the Si–H bond of silanes, disilanes, and siloxanes, leading to the exclus...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9490852/ https://www.ncbi.nlm.nih.gov/pubmed/35648453 http://dx.doi.org/10.1021/jacs.2c03739 |