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Oxidatively induced reactivity in Rh(iii)-catalyzed 7-azaindole synthesis: insights into the role of the silver additive

A typical synthetic protocol for preparing 7-azaindoles involves the coupling of 2-aminopyridine and alkyne substrates using a Rh(iii)-catalyst. The catalysis requires the assistance of an external Ag(+) oxidant that is thought to regenerate the catalyst and increase the turnover efficiency. Density...

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Detalles Bibliográficos
Autores principales: Ryu, Ho, Pudasaini, Bimal, Cho, Dasol, Hong, Sungwoo, Baik, Mu-Hyun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9491069/
https://www.ncbi.nlm.nih.gov/pubmed/36320687
http://dx.doi.org/10.1039/d2sc01650h