Unified synthesis of multiply arylated alkanes by catalytic deoxygenative transformation of diarylketones

A deoxygenative transformation of diarylketones leading to multiply arylated alkanes was developed. Diarylketones were reacted with diphenylphosphine oxide resulting in a phospha-Brook rearrangement, followed by palladium-catalyzed cross-couplings or a Friedel–Crafts type alkylation to afford the co...

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Detalles Bibliográficos
Autores principales: Kurosawa, Miki B., Kato, Kenta, Muto, Kei, Yamaguchi, Junichiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9491083/
https://www.ncbi.nlm.nih.gov/pubmed/36320688
http://dx.doi.org/10.1039/d2sc03720c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9491083/
https://www.ncbi.nlm.nih.gov/pubmed/36320688
http://dx.doi.org/10.1039/d2sc03720c

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