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Chiral diboranes as catalysts for the stereoselective organopolymerization of epoxides
It is demonstrated that stereoselective polymerization of epoxides, long a domain of metal-based compounds, can also be achieved via the application of organocatalysts. A simple two-step synthesis starting from widely available 1,1′-bi-2-naphthol (BINOL) backbones yields diboranes which, in tandem w...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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The Royal Society of Chemistry
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9491197/ https://www.ncbi.nlm.nih.gov/pubmed/36320696 http://dx.doi.org/10.1039/d2sc03977j |