Generation of boryl-nitroxide radicals from a boraalkene via the nitroso ene reaction

Examples of isolated boron substituted nitroxide radicals are rare. The reaction of the reactive cyclic boraalkene 3 with nitrosobenzene yields a mixture of the [2 + 2] cycloaddition product 4a, the B-nitroxide radicals 5a and 6a and the azoxybenzene co-product 7avia a bora nitroso ene reaction path...

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Detalles Bibliográficos
Autores principales: Chen, Chaohuang, Daniliuc, Constantin G., Klabunde, Sina, Hansen, Michael Ryan, Kehr, Gerald, Erker, Gerhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9491209/
https://www.ncbi.nlm.nih.gov/pubmed/36320693
http://dx.doi.org/10.1039/d2sc02485c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9491209/
https://www.ncbi.nlm.nih.gov/pubmed/36320693
http://dx.doi.org/10.1039/d2sc02485c

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