The Steric Effect in Preparations of Vanadium(II)/(III) Dinitrogen Complexes of Triamidoamine Ligands Bearing Bulky Substituents

The reactions of newly designed lithiated triamidoamines Li(3)L(R) (R = iPr, Pen, and Cy(2)) with VCl(3)(THF)(3) under N(2) yielded dinitrogen–divanadium complexes with a μ-N(2) between vanadium atoms [{V(L(R))}(2)(μ-N(2))] (R = iPr (1) and Pen (2)) for the former two, while not dinitrogen–divanadiu...

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Detalles Bibliográficos
Autores principales: Kokubo, Yoshiaki, Igarashi, Itsuki, Nakao, Kenichi, Hachiya, Wataru, Kugimiya, Shinichi, Ozawa, Tomohiro, Masuda, Hideki, Kajita, Yuji
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9500765/
https://www.ncbi.nlm.nih.gov/pubmed/36144600
http://dx.doi.org/10.3390/molecules27185864

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9500765/
https://www.ncbi.nlm.nih.gov/pubmed/36144600
http://dx.doi.org/10.3390/molecules27185864

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