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The Steric Effect in Preparations of Vanadium(II)/(III) Dinitrogen Complexes of Triamidoamine Ligands Bearing Bulky Substituents
The reactions of newly designed lithiated triamidoamines Li(3)L(R) (R = iPr, Pen, and Cy(2)) with VCl(3)(THF)(3) under N(2) yielded dinitrogen–divanadium complexes with a μ-N(2) between vanadium atoms [{V(L(R))}(2)(μ-N(2))] (R = iPr (1) and Pen (2)) for the former two, while not dinitrogen–divanadiu...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9500765/ https://www.ncbi.nlm.nih.gov/pubmed/36144600 http://dx.doi.org/10.3390/molecules27185864 |