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Stereoselective Synthesis of Polysubstituted Spiropentanes

[Image: see text] A new approach to polysubstituted spiropentanes is developed through a regio- and diastereoselective carbometalation of sp(2)-disubstituted cyclopropenes. The control of selectivity originates from a combined syn-facial diastereoselective carbometalation with a regio-directed addit...

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Detalles Bibliográficos
Autores principales: Cohen, Yair, Toledano, Dor, Marek, Ilan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9501800/
https://www.ncbi.nlm.nih.gov/pubmed/36088586
http://dx.doi.org/10.1021/jacs.2c07370