Catalytic Synthesis of Cyclopropenium Cations with Rh-Carbynoids

[Image: see text] Herein, we report the first catalytic one-step synthesis of cyclopropenium cations (CPCs) with readily available alkynes and hypervalent iodine reagents as carbyne sources. Key to the process is the catalytic generation of a novel Rh-carbynoid that formally transfers monovalent cat...

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Detalles Bibliográficos
Autores principales: Tu, Hang-Fei, Jeandin, Aliénor, Suero, Marcos G.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9501905/
https://www.ncbi.nlm.nih.gov/pubmed/36074785
http://dx.doi.org/10.1021/jacs.2c07769

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9501905/
https://www.ncbi.nlm.nih.gov/pubmed/36074785
http://dx.doi.org/10.1021/jacs.2c07769

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