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Tris(2-Pyridyl)Arsine as a New Platform for Design of Luminescent Cu(I) and Ag(I) Complexes

The coordination behavior of tris(2-pyridyl)arsine (Py(3)As) has been studied for the first time on the example of the reactions with CuI, CuBr and AgClO(4). When treated with CuI in CH(2)Cl(2) medium, Py(3)As unexpectedly affords the scorpionate complex [Cu(Py(3)As)I]∙CH(2)Cl(2) only, while this re...

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Detalles Bibliográficos
Autores principales: Demyanov, Yan V., Sadykov, Evgeniy H., Rakhmanova, Marianna I., Novikov, Alexander S., Bagryanskaya, Irina Yu., Artem’ev, Alexander V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9503387/
https://www.ncbi.nlm.nih.gov/pubmed/36144790
http://dx.doi.org/10.3390/molecules27186059