Insights into gold-catalyzed formation of aza-heterocycles using benzofuroxans as nitrene transfer reagents: mechanism and origins of chemoselectivity

Density functional theory (DFT) calculations have been performed to reveal the mechanism of gold(i)-catalyzed annulation of N-allylynamides and benzofuroxans as nitrene transfer reagents to construct azaheterocyclic compounds. The calculated results revealed that the reaction mechanism mainly underg...

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Detalles Bibliográficos
Autores principales: Wu, Weirong, Liang, Jiehui, Jiang, Biaolin, Tian, Xiaoxuan, Li, Tingzhen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9516356/
https://www.ncbi.nlm.nih.gov/pubmed/36276040
http://dx.doi.org/10.1039/d2ra05382a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9516356/
https://www.ncbi.nlm.nih.gov/pubmed/36276040
http://dx.doi.org/10.1039/d2ra05382a

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