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Racemization Pathway for MoO(2)(acac)(2) Favored over Ray–Dutt, Bailar, and Conte–Hippler Twists
[Image: see text] Chiral cis-MoO(2)(acac)(2) racemizes via four pathways that agree with and extend upon Muetterties’ topological analysis for dynamic MX(2)(chel)(2) complexes. Textbook Ray–Dutt and Bailar twists are the least favored with barriers of 27.5 and 28.7 kcal/mol, respectively. Rotating b...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9516665/ https://www.ncbi.nlm.nih.gov/pubmed/35980189 http://dx.doi.org/10.1021/acs.inorgchem.2c00824 |