Synthesis of Electrophiles Derived from Dimeric Aminoboranes and Assessing Their Utility in the Borylation of π Nucleophiles

[Image: see text] Dimeric aminoboranes, [H(2)BNR(2)](2) (R = Me or CH(2)CH(2)) containing B(2)N(2) cores, can be activated by I(2), HNTf(2) (NTf(2) = [N(SO(2)CF(3))(2)]), or [Ph(3)C][B(C(6)F(5))(4)] to form isolable H(2)B(μ-NR(2))(2)BHX (for X = I or NTf(2)). For X = [B(C(6)F(5))(4)](−) further reac...

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Detalles Bibliográficos
Autores principales: Millet, Clément R. P., Pahl, Jürgen, Noone, Emily, Yuan, Kang, Nichol, Gary S., Uzelac, Marina, Ingleson, Michael J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9516688/
https://www.ncbi.nlm.nih.gov/pubmed/36185396
http://dx.doi.org/10.1021/acs.organomet.2c00393

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9516688/
https://www.ncbi.nlm.nih.gov/pubmed/36185396
http://dx.doi.org/10.1021/acs.organomet.2c00393

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