Investigating the role of the strong field ligands in [FeFe] hydrogenase: spectroscopic and functional characterization of a semi-synthetic mono-cyanide active site

Artificial maturation of hydrogenases provides a path towards generating new semi-synthetic enzymes with novel catalytic properties. Here enzymes featuring a synthetic asymmetric mono-cyanide cofactor have been prepared using two different hydrogenase scaffolds. Their structure and reactivity was in...

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Detalles Bibliográficos
Autores principales: Lorenzi, Marco, Gellett, Joe, Zamader, Afridi, Senger, Moritz, Duan, Zehui, Rodríguez-Maciá, Patricia, Berggren, Gustav
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9516953/
https://www.ncbi.nlm.nih.gov/pubmed/36320473
http://dx.doi.org/10.1039/d2sc02271k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9516953/
https://www.ncbi.nlm.nih.gov/pubmed/36320473
http://dx.doi.org/10.1039/d2sc02271k

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