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Investigating the role of the strong field ligands in [FeFe] hydrogenase: spectroscopic and functional characterization of a semi-synthetic mono-cyanide active site
Artificial maturation of hydrogenases provides a path towards generating new semi-synthetic enzymes with novel catalytic properties. Here enzymes featuring a synthetic asymmetric mono-cyanide cofactor have been prepared using two different hydrogenase scaffolds. Their structure and reactivity was in...
Autores principales: | Lorenzi, Marco, Gellett, Joe, Zamader, Afridi, Senger, Moritz, Duan, Zehui, Rodríguez-Maciá, Patricia, Berggren, Gustav |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9516953/ https://www.ncbi.nlm.nih.gov/pubmed/36320473 http://dx.doi.org/10.1039/d2sc02271k |
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