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Union carbide polymerization catalysts: from uncovering active site structures to designing molecularly-defined analogs

The Union Carbide (UC) ethylene polymerization catalysts, based on chromocene dispersed on silica, show distinct features from the Phillips catalysts, but share the same heated debate regarding the structure of their active sites. Based on a combination of IR, EPR spectroscopies, labeling experiment...

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Detalles Bibliográficos
Autores principales: Trummer, David, Nobile, Anna Giorgia, Payard, Pierre-Adrien, Ashuiev, Anton, Kakiuchi, Yuya, Klose, Daniel, Jeschke, Gunnar, Copéret, Christophe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9517275/
https://www.ncbi.nlm.nih.gov/pubmed/36320461
http://dx.doi.org/10.1039/d2sc04235e