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Synthesis of carbinoxamine via α-C(sp(3))–H 2-pyridylation of O, S or N-containing compounds enabled by non-D–A-type super organoreductants and sulfoxide- or sulfide HAT reagents

The radical cations of tertiary amines (R(3)N) have been well-established as the precursors of HAT reagents in photochemical transformations. Similarly, thiols and thioacids bearing SH groups have also been widely applied as HAT reagents. Despite the fact that sulfoxides (R(2)SO) and sulfides (RSR)...

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Detalles Bibliográficos
Autores principales: Cui, Xian-Chao, Zhang, Hu, Wang, Yi-Ping, Qu, Jian-Ping, Kang, Yan-Biao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9517729/
https://www.ncbi.nlm.nih.gov/pubmed/36320488
http://dx.doi.org/10.1039/d2sc03504a