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Synthesis of carbinoxamine via α-C(sp(3))–H 2-pyridylation of O, S or N-containing compounds enabled by non-D–A-type super organoreductants and sulfoxide- or sulfide HAT reagents
The radical cations of tertiary amines (R(3)N) have been well-established as the precursors of HAT reagents in photochemical transformations. Similarly, thiols and thioacids bearing SH groups have also been widely applied as HAT reagents. Despite the fact that sulfoxides (R(2)SO) and sulfides (RSR)...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9517729/ https://www.ncbi.nlm.nih.gov/pubmed/36320488 http://dx.doi.org/10.1039/d2sc03504a |