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Ferrocenoyl-adenines: substituent effects on regioselective acylation

A series of N(6)-substituted adenine–ferrocene conjugates was prepared and the reaction mechanism underlying the synthesis was explored. The S(N)2-like reaction between ferrocenoyl chloride and adenine anions is a regioselective process in which the product ratio (N7/N9-ferrocenoyl isomers) is gover...

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Detalles Bibliográficos
Autores principales: Toma, Mateja, Zubčić, Gabrijel, Lapić, Jasmina, Djaković, Senka, Šakić, Davor, Vrček, Valerije
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9520867/
https://www.ncbi.nlm.nih.gov/pubmed/36225728
http://dx.doi.org/10.3762/bjoc.18.133