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Complex Magnetic Order in Topochemically Reduced Rh(I)/Rh(III) LaM(0.5)Rh(0.5)O(2.25) (M = Co, Ni) Phases

[Image: see text] Topochemical reduction of the cation-disordered perovskite oxides LaCo(0.5)Rh(0.5)O(3) and LaNi(0.5)Rh(0.5)O(3) with Zr yields the partially anion-vacancy ordered phases LaCo(0.5)Rh(0.5)O(2.25) and LaNi(0.5)Rh(0.5)O(2.25), respectively. Neutron diffraction and Hard X-ray photoelect...

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Detalles Bibliográficos
Autores principales: Xu, Zheying, Thakur, Pardeep K., Lee, Tien-Lin, Regoutz, Anna, Suard, Emmanuelle, Puente-Orench, Inés, Hayward, Michael A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9533305/
https://www.ncbi.nlm.nih.gov/pubmed/36129165
http://dx.doi.org/10.1021/acs.inorgchem.2c02747