Synthesis, structure and reactivity of μ(3)-SnH capped trinuclear nickel cluster

Treatment of the trichlorotin-capped trinuclear nickel cluster, [Ni(3)(dppm)(3)(μ(3)-Cl)(μ(3)-SnCl(3))], 1, with 4 eq. NaHB(Et)(3) yields a μ(3)-SnH capped trinuclear nickel cluster, [Ni(3)(dppm)(3)(μ(3)-H)(μ(3)-SnH)], 2 [dppm = bis(diphenylphosphino)methane]. Single-crystal X-ray diffraction, nucle...

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Detalles Bibliográficos
Autores principales: Torquato, Nicole A., Palasz, Joseph M., Bertrand, Quentin C., Brunner, Felix M., Chan, Thomas, Gembicky, Milan, Mrse, Anthony A., Kubiak, Clifford P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9533397/
https://www.ncbi.nlm.nih.gov/pubmed/36320577
http://dx.doi.org/10.1039/d2sc04042e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9533397/
https://www.ncbi.nlm.nih.gov/pubmed/36320577
http://dx.doi.org/10.1039/d2sc04042e

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