Assembling diuranium complexes in different states of charge with a bridging redox-active ligand

Radical-bridged diuranium complexes are desirable for their potential high exchange coupling and single molecule magnet (SMM) behavior, but remain rare. Here we report for the first time radical-bridged diuranium(iv) and diuranium(iii) complexes. Reaction of [U{N(SiMe(3))(2)}(3)] with 2,2′-bipyrimid...

Descripción completa

Detalles Bibliográficos
Autores principales: Modder, Dieuwertje K., Batov, Mikhail S., Rajeshkumar, Thayalan, Sienkiewicz, Andrzej, Zivkovic, Ivica, Scopelliti, Rosario, Maron, Laurent, Mazzanti, Marinella
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9533398/
https://www.ncbi.nlm.nih.gov/pubmed/36320571
http://dx.doi.org/10.1039/d2sc03592h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9533398/
https://www.ncbi.nlm.nih.gov/pubmed/36320571
http://dx.doi.org/10.1039/d2sc03592h

Ejemplares similares