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Silver-Catalyzed Controlled Intermolecular Cross-Coupling of Silyl Enol Ethers: Scalable Access to 1,4-Diketones

[Image: see text] A protocol for silver-catalyzed controlled intermolecular cross-coupling of silyl enolates is disclosed. The protocol displays good functional group tolerance and allows efficient preparation of a series of synthetically useful 1,4-diketones. Preliminary mechanistic investigations...

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Detalles Bibliográficos
Autores principales: Xu, Li, Liu, Xiaoyi, Alvey, Gregory R., Shatskiy, Andrey, Liu, Jian-Quan, Kärkäs, Markus D., Wang, Xiang-Shan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9536665/
https://www.ncbi.nlm.nih.gov/pubmed/35713416
http://dx.doi.org/10.1021/acs.orglett.2c01477