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Heavy‐Atom Quantum Tunnelling in Spin Crossovers of Nitrenes
We simulate two recent matrix‐isolation experiments at cryogenic temperatures, in which a nitrene undergoes spin crossover from its triplet state to a singlet state via quantum tunnelling. We detail the failure of the commonly applied weak‐coupling method (based on a linear approximation of the pote...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9540336/ https://www.ncbi.nlm.nih.gov/pubmed/35698730 http://dx.doi.org/10.1002/anie.202206314 |