Stable Two‐Legged Parent Piano‐Stool and Mixed Diborabenzene‐E(4) (E=P, As) Sandwich Complexes of Group 8

A cyclic alkyl(amino)carbene‐stabilized 1,4‐diborabenzene (DBB) ligand enables the isolation of 18‐electron two‐legged parent piano‐stool Fe(0) and Ru(0) complexes, [(η(6)‐DBB)M(CO)(2)], the ruthenium complex being the first of its kind to be structurally characterized. [(η(6)‐DBB)Fe(CO)(2)] reacts...

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Detalles Bibliográficos
Autores principales: Dietz, Maximilian, Arrowsmith, Merle, Reichl, Stephan, Lugo‐Fuentes, Leonardo I., Jiménez‐Halla, J. Oscar C., Scheer, Manfred, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9540419/
https://www.ncbi.nlm.nih.gov/pubmed/35781917
http://dx.doi.org/10.1002/anie.202206840

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9540419/
https://www.ncbi.nlm.nih.gov/pubmed/35781917
http://dx.doi.org/10.1002/anie.202206840

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