Evidence of substrate binding and product release via belt-sulfur mobilization of the nitrogenase cofactor

The Mo-nitrogenase catalyses the ambient reduction of N(2) to NH(3) at the M-cluster, a complex cofactor that comprises two metal-sulphur partial cubanes ligated by an interstitial carbide and three belt-sulphurs. A recent crystallographic study suggests binding of N(2) via displacement of the belt-...

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Detalles Bibliográficos
Autores principales: Lee, Chi Chung, Kang, Wonchull, Jasniewski, Andrew J., Stiebritz, Martin T., Tanifuji, Kazuki, Ribbe, Markus W., Hu, Yilin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9540607/
https://www.ncbi.nlm.nih.gov/pubmed/36213009
http://dx.doi.org/10.1038/s41929-022-00782-7

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9540607/
https://www.ncbi.nlm.nih.gov/pubmed/36213009
http://dx.doi.org/10.1038/s41929-022-00782-7

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