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Evidence of substrate binding and product release via belt-sulfur mobilization of the nitrogenase cofactor
The Mo-nitrogenase catalyses the ambient reduction of N(2) to NH(3) at the M-cluster, a complex cofactor that comprises two metal-sulphur partial cubanes ligated by an interstitial carbide and three belt-sulphurs. A recent crystallographic study suggests binding of N(2) via displacement of the belt-...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9540607/ https://www.ncbi.nlm.nih.gov/pubmed/36213009 http://dx.doi.org/10.1038/s41929-022-00782-7 |