Umpolung of an Aliphatic Ketone to a Magnesium Ketone‐1,2‐diide Complex with Vicinal Dianionic Charge

The new β‐diketimine ( iPrDip)nacnacH, HC(iPrCNDip)(2)H, Dip=2,6‐iPr(2)‐C(6)H(3), was converted to the magnesium(I) complex [{(( iPrDip)nacnac)Mg}(2)] and reaction with 2‐adamantanone (OAd) afforded the ketone‐1,2‐diide complex [{(( iPrDip)nacnac)Mg}(2)(μ‐OAd)]. The complex contains the first stable...

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Detalles Bibliográficos
Autores principales: Burnett, Stuart, Bourne, Connor, Slawin, Alexandra M. Z., van Mourik, Tanja, Stasch, Andreas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541192/
https://www.ncbi.nlm.nih.gov/pubmed/35762819
http://dx.doi.org/10.1002/anie.202204472

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541192/
https://www.ncbi.nlm.nih.gov/pubmed/35762819
http://dx.doi.org/10.1002/anie.202204472

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