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Umpolung of an Aliphatic Ketone to a Magnesium Ketone‐1,2‐diide Complex with Vicinal Dianionic Charge
The new β‐diketimine ( iPrDip)nacnacH, HC(iPrCNDip)(2)H, Dip=2,6‐iPr(2)‐C(6)H(3), was converted to the magnesium(I) complex [{(( iPrDip)nacnac)Mg}(2)] and reaction with 2‐adamantanone (OAd) afforded the ketone‐1,2‐diide complex [{(( iPrDip)nacnac)Mg}(2)(μ‐OAd)]. The complex contains the first stable...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541192/ https://www.ncbi.nlm.nih.gov/pubmed/35762819 http://dx.doi.org/10.1002/anie.202204472 |