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Mechanistic Studies on the Epoxidation of Alkenes by Macrocyclic Manganese Porphyrin Catalysts

Macrocyclic metal porphyrin complexes can act as shape‐selective catalysts mimicking the action of enzymes. To achieve enzyme‐like reactivity, a mechanistic understanding of the reaction at the molecular level is needed. We report a mechanistic study of alkene epoxidation by the oxidant iodosylbenze...

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Detalles Bibliográficos
Autores principales: Chen, Xiaofei, Duez, Quentin, Tripodi, Guilherme L., Gilissen, Pieter J., Piperoudis, Dimitrios, Tinnemans, Paul, Elemans, Johannes A. A. W., Roithová, Jana, Nolte, Roeland J. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541230/
https://www.ncbi.nlm.nih.gov/pubmed/36249861
http://dx.doi.org/10.1002/ejoc.202200280