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Umpolung in a Pair of Cobalt(III) Terminal Imido/Imidyl Complexes
Reaction of the Co(I) complex [(TIMMN(mes))Co(I)](PF(6)) (1) (TIMMN(mes)= tris‐[2‐(3‐mesityl‐imidazolin‐2‐ylidene)‐methyl]amine) with mesityl azide yields the Co(III) imide [(TIMMN(mes))Co(III)(NMes)](PF(6)) (2). Oxidation of 2 with [FeCp(2)](PF(6)) provides access to a rare Co(III) imidyl [(TIMMN(m...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541304/ https://www.ncbi.nlm.nih.gov/pubmed/35674679 http://dx.doi.org/10.1002/anie.202206848 |