Umpolung in a Pair of Cobalt(III) Terminal Imido/Imidyl Complexes

Reaction of the Co(I) complex [(TIMMN(mes))Co(I)](PF(6)) (1) (TIMMN(mes)= tris‐[2‐(3‐mesityl‐imidazolin‐2‐ylidene)‐methyl]amine) with mesityl azide yields the Co(III) imide [(TIMMN(mes))Co(III)(NMes)](PF(6)) (2). Oxidation of 2 with [FeCp(2)](PF(6)) provides access to a rare Co(III) imidyl [(TIMMN(m...

Descripción completa

Detalles Bibliográficos
Autores principales: Mao, Weiqing, Fehn, Dominik, Heinemann, Frank W., Scheurer, Andreas, van Gastel, Maurice, Jannuzzi, Sergio A. V., DeBeer, Serena, Munz, Dominik, Meyer, Karsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541304/
https://www.ncbi.nlm.nih.gov/pubmed/35674679
http://dx.doi.org/10.1002/anie.202206848

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541304/
https://www.ncbi.nlm.nih.gov/pubmed/35674679
http://dx.doi.org/10.1002/anie.202206848

Ejemplares similares