Cargando…

Umpolung in a Pair of Cobalt(III) Terminal Imido/Imidyl Complexes

Reaction of the Co(I) complex [(TIMMN(mes))Co(I)](PF(6)) (1) (TIMMN(mes)= tris‐[2‐(3‐mesityl‐imidazolin‐2‐ylidene)‐methyl]amine) with mesityl azide yields the Co(III) imide [(TIMMN(mes))Co(III)(NMes)](PF(6)) (2). Oxidation of 2 with [FeCp(2)](PF(6)) provides access to a rare Co(III) imidyl [(TIMMN(m...

Descripción completa

Detalles Bibliográficos
Autores principales:	Mao, Weiqing, Fehn, Dominik, Heinemann, Frank W., Scheurer, Andreas, van Gastel, Maurice, Jannuzzi, Sergio A. V., DeBeer, Serena, Munz, Dominik, Meyer, Karsten
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541304/ https://www.ncbi.nlm.nih.gov/pubmed/35674679 http://dx.doi.org/10.1002/anie.202206848

Ejemplares similares

A Pair of Cobalt(III/IV) Terminal Imido Complexes
por: Mao, Weiqing, et al.
Publicado: (2021)

High‐Spin Imido Cobalt Complexes with Imidyl Radical Character
por: Reckziegel, Alexander, et al.
Publicado: (2021)

Between imide, imidyl and nitrene – an imido iron complex in two oxidation states
por: Reith, Sascha, et al.
Publicado: (2022)

Cobalt Diazo‐Compounds: From Nitrilimide to Isocyanoamide via a Diazomethanediide Fleeting Intermediate
por: Aghazada, Sadig, et al.
Publicado: (2021)

C−H Bond Activation by an Imido Cobalt(III) and the Resulting Amido Cobalt(II) Complex
por: Reckziegel, Alexander, et al.
Publicado: (2020)

Rhenium-Imido Corroles
por: Alemayehu, Abraham B., et al.
Publicado: (2020)

A Terminal Iron Nitrilimine Complex: Accessing the Terminal Nitride through Diazo N−N Bond Cleavage
por: Aghazada, Sadig, et al.
Publicado: (2019)

Synthesis of Tungsten Imido Alkylidene Complexes that Contain an Electron-Withdrawing Imido Ligand
por: Axtell, Jonathan C., et al.
Publicado: (2014)

Metathesis of a U(V) imido complex: a route to a terminal U(V) sulfide
por: Kelly, Rory P., et al.
Publicado: (2017)

1,2-Addition and cycloaddition reactions of niobium bis(imido) and oxo imido complexes
por: Fostvedt, Jade I., et al.
Publicado: (2020)

Stabilization of a high-spin three-coordinate Fe(iii) imidyl complex by radical delocalization
por: Yang, Po-Chun, et al.
Publicado: (2022)

Molybdenum(VI) Bis(imido) Complexes: From Frustrated Lewis Pairs to Weakly Coordinating Cations
por: Milinkovic, Angela, et al.
Publicado: (2022)

How to tame a palladium terminal oxo
por: Munz, Dominik
Publicado: (2017)

Umpolung Amide Synthesis Using Substoichiometric N-Iodosuccinimide (NIS) and Oxygen as a Terminal Oxidant
por: Schwieter, Kenneth E., et al.
Publicado: (2014)

Catalytic Asymmetric Umpolung Reactions of Imines
por: Wu, Yongwei, et al.
Publicado: (2015)

Umpolung strategies for the functionalization of peptides and proteins
por: White, Andrew M., et al.
Publicado: (2022)

An iridium(iii/iv/v) redox series featuring a terminal imido complex with triplet ground state
por: Kinauer, Markus, et al.
Publicado: (2018)

New Volatile Tantalum Imido Precursors with Carboxamide Ligands
por: Hwang, Jeong Min, et al.
Publicado: (2021)

‘Umpolung’ Reactivity in Semiaqueous Amide and Peptide Synthesis
por: Shen, Bo, et al.
Publicado: (2010)

Redox-induced umpolung of transition metal carbenes
por: Cui, Peng, et al.
Publicado: (2015)

An α‐Cyclopropanation of Carbonyl Derivatives by Oxidative Umpolung
por: Bauer, Adriano, et al.
Publicado: (2020)

An umpolung strategy to react catalytic enols with nucleophiles
por: Sanz-Marco, Amparo, et al.
Publicado: (2019)

Catalytic Generation of Carbanions through Carbonyl Umpolung
por: Wang, Shun, et al.
Publicado: (2021)

Electrochemical Umpolung C–H Functionalization of Oxindoles
por: Pastor, Miryam, et al.
Publicado: (2021)

An Expedient Method for the Umpolung Coupling of Enols with Heteronucleophiles
por: García‐Vázquez, Víctor, et al.
Publicado: (2022)

Synthesis and Characterization of an f-Block Terminal Parent Imido [U=NH] Complex: A Masked Uranium(IV) Nitride
por: King, David M., et al.
Publicado: (2014)

Synthesis of Fe(III) and Fe(IV) Cyanide Complexes Using Hypervalent Iodine Reagents as Cyano‐Transfer One‐Electron Oxidants
por: Souilah, Charafa, et al.
Publicado: (2022)

An Umpolung Approach for the Chemoselective Arylation of Selenocysteine in Unprotected Peptides
por: Cohen, Daniel T., et al.
Publicado: (2015)

Ruthenium-catalyzed umpolung carboxylation of hydrazones with CO(2)
por: Yan, Si-Shun, et al.
Publicado: (2018)

Synthesis of Novel Heterocycles by Amide Activation and Umpolung Cyclization
por: Zhang, Haoqi, et al.
Publicado: (2020)

Umpolung carbonyls enable direct allylation and olefination of carbohydrates
por: Kan, Jian, et al.
Publicado: (2022)

Hypoiodite-Catalyzed Oxidative Umpolung of Indoles for Enantioselective Dearomatization
por: Tanaka, Hiroki, et al.
Publicado: (2022)

Dual Role of Silver Moieties Coupled with Ordered Mesoporous Cobalt Oxide towards Electrocatalytic Oxygen Evolution Reaction
por: Yu, Mingquan, et al.
Publicado: (2020)

Surface Boron Modulation on Cobalt Oxide Nanocrystals for Electrochemical Oxygen Evolution Reaction
por: Yu, Mingquan, et al.
Publicado: (2022)

Substitution Effect on the Charge Transfer Processes in Organo-Imido Lindqvist-Polyoxomolybdate
por: Hermosilla-Ibáñez, Patricio, et al.
Publicado: (2018)

Amide Synthesis through the In Situ Generation of Chloro- and Imido-Phosphonium Salts
por: Irving, Charles D., et al.
Publicado: (2020)

Cobalt and Iron Stabilized Ketyl, Ketiminyl and Aldiminyl Radical Anions
por: Sieg, Grégoire, et al.
Publicado: (2021)

Diazomethane umpolung atop anthracene: an electrophilic methylene transfer reagent
por: Joost, Maximilian, et al.
Publicado: (2017)

Metal-Dependent Umpolung Reactivity of Carbenes Derived from Cyclopropenes
por: Zhang, Dan, et al.
Publicado: (2019)

An umpolung reaction of α-iminothioesters possessing a cyclopropyl group
por: Shimizu, Makoto, et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_lk9e2kolg1rvpoa2lab1prsdl0