Intramolecular Tricarbonyl‐Ene Reactions and α‐Hydroxy‐β‐Diketone Rearrangements Inspired by the Biosynthesis of Polycyclic Polyprenylated Acylphloroglucinols

Structurally unique natural products pose biosynthetic puzzles whose solution can inspire new chemical reactions. Herein, we propose a unified biosynthetic pathway towards some complex meroterpenoids—the hyperireflexolides, biyoulactones, hybeanones and hypermonones. This hypothesis led to the disco...

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Detalles Bibliográficos
Autores principales: zur Bonsen, Andreas B., Peralta, Ricardo A., Fallon, Thomas, Huang, David M., George, Jonathan H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541541/
https://www.ncbi.nlm.nih.gov/pubmed/35680561
http://dx.doi.org/10.1002/anie.202203311

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541541/
https://www.ncbi.nlm.nih.gov/pubmed/35680561
http://dx.doi.org/10.1002/anie.202203311

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