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Visible‐Light‐Responsive Self‐Assembled Complexes: Improved Photoswitching Properties by Metal Ion Coordination
A photoswitchable ligand based on azobenzene is self‐assembled with palladium(II) ions to form a [Pd(2)(E‐L)(4)](4+) cage. Irradiation with 470 nm light results in the near‐quantitative switching to a monomeric species [Pd(Z‐L)(2)](2+), which can be reversed by irradiation with 405 nm light, or heat...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541570/ https://www.ncbi.nlm.nih.gov/pubmed/35972841 http://dx.doi.org/10.1002/anie.202205701 |