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Binding, Release and Functionalization of Intact Pnictogen Tetrahedra Coordinated to Dicopper Complexes

The bridging MeCN ligand in the dicopper(I) complexes [(DPFN)Cu(2)(μ,η(1) : η(1)‐MeCN)][X](2) (X=weakly coordinating anion, NTf(2) (1 a), FAl[OC(6)F(10)(C(6)F(5))](3) (1 b), Al[OC(CF(3))(3)](4) (1 c)) was replaced by white phosphorus (P(4)) or yellow arsenic (As(4)) to yield [(DPFN)Cu(2)(μ,η(2) : η(...

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Detalles Bibliográficos
Autores principales: Piesch, Martin, Nicolay, Amélie, Haimerl, Maria, Seidl, Michael, Balázs, Gábor, Don Tilley, T., Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541576/
https://www.ncbi.nlm.nih.gov/pubmed/35575052
http://dx.doi.org/10.1002/chem.202201144