Lewis Acid Assisted Brønsted Acid Catalysed Decarbonylation of Isocyanates: A Combined DFT and Experimental Study

An efficient and mild reaction protocol for the decarbonylation of isocyanates has been developed using catalytic amounts of Lewis acidic boranes. The electronic nature (electron withdrawing, electron neutral, and electron donating) and the position of the substituents (ortho/meta/para) bound to iso...

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Detalles Bibliográficos
Autores principales: Dasgupta, Ayan, van Ingen, Yara, Guerzoni, Michael G., Farshadfar, Kaveh, Rawson, Jeremy M., Richards, Emma, Ariafard, Alireza, Melen, Rebecca L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541586/
https://www.ncbi.nlm.nih.gov/pubmed/35560742
http://dx.doi.org/10.1002/chem.202201422

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541586/
https://www.ncbi.nlm.nih.gov/pubmed/35560742
http://dx.doi.org/10.1002/chem.202201422

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