Synthesis, Characterization and Reactivity of a σ‐Donating Ni(0)‐Stabilized Silyliumylidene Ion

The synthesis of a silyliumylidene cation complex 2 stabilized by a Ni(0)‐based donating ligand is reported. Experimental and theoretical studies demonstrate that the highly electrophilic Si(II) center is stabilized by a dative Ni→Si σ‐interaction and π‐donations from the amino‐ and Ni‐moieties. Due...

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Detalles Bibliográficos
Autores principales: Takahashi, Shintaro, Frutos, María, Baceiredo, Antoine, Madec, David, Saffon‐Merceron, Nathalie, Branchadell, Vicenç, Kato, Tsuyoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541621/
https://www.ncbi.nlm.nih.gov/pubmed/35880424
http://dx.doi.org/10.1002/anie.202208202

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541621/
https://www.ncbi.nlm.nih.gov/pubmed/35880424
http://dx.doi.org/10.1002/anie.202208202

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