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Synthesis, Characterization and Reactivity of a σ‐Donating Ni(0)‐Stabilized Silyliumylidene Ion
The synthesis of a silyliumylidene cation complex 2 stabilized by a Ni(0)‐based donating ligand is reported. Experimental and theoretical studies demonstrate that the highly electrophilic Si(II) center is stabilized by a dative Ni→Si σ‐interaction and π‐donations from the amino‐ and Ni‐moieties. Due...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541621/ https://www.ncbi.nlm.nih.gov/pubmed/35880424 http://dx.doi.org/10.1002/anie.202208202 |