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Dual Reactivity of a Geometrically Constrained Phosphenium Cation
A geometrically constrained phosphenium cation in bis(pyrrolyl)pyridine based NNN pincer type ligand (1(+) ) was synthesized, isolated and its preliminary reactivity was studied with small molecules. 1(+) reacts with MeOH and Et(2)NH, activating the O−H and N−H bonds via a P‐center/ligand assisted p...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541694/ https://www.ncbi.nlm.nih.gov/pubmed/35830679 http://dx.doi.org/10.1002/anie.202208401 |