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Photocatalytic E→Z Contra‐Thermodynamic Isomerization of Vinyl Silanes with Lewis Base
Herein, we disclosed the contra‐thermodynamic E→Z isomerization of alkenyl silanes, according to the in situ formation of a chromophoric species, in the presence of rac‐BINAP as the catalyst. The reaction carried out in DMSO or CH(3)CN under irradiation at 405 nm allowed the interconversion of the E...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541780/ https://www.ncbi.nlm.nih.gov/pubmed/35652371 http://dx.doi.org/10.1002/chem.202201514 |