Cargando…

Photocatalytic E→Z Contra‐Thermodynamic Isomerization of Vinyl Silanes with Lewis Base

Herein, we disclosed the contra‐thermodynamic E→Z isomerization of alkenyl silanes, according to the in situ formation of a chromophoric species, in the presence of rac‐BINAP as the catalyst. The reaction carried out in DMSO or CH(3)CN under irradiation at 405 nm allowed the interconversion of the E...

Descripción completa

Detalles Bibliográficos
Autores principales:	Le, Thi Minh Thi, Brégent, Thibaud, Jubault, Philippe, Poisson, Thomas
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541780/ https://www.ncbi.nlm.nih.gov/pubmed/35652371 http://dx.doi.org/10.1002/chem.202201514

Ejemplares similares

Continuous‐Flow Divergent Lithiation of 2,3‐Dihalopyridines: Deprotolithiation versus Halogen Dance
por: Brégent, Thibaud, et al.
Publicado: (2022)

Electrochemical Synthesis of gem‐Difluoro‐ and γ‐Fluoro‐Allyl Boronates and Silanes
por: Aelterman, Maude, et al.
Publicado: (2022)

Photocatalytic Isomerization of (E)-Anethole to (Z)-Anethole
por: Korff, Marvin, et al.
Publicado: (2022)

Mechanistic aspects of the isomerization of Z-vinylic tellurides double bonds in the synthesis of potassium Z-vinyltrifluoroborate salts
por: Stefani, Hélio A, et al.
Publicado: (2008)

Thermodynamics of the Isomerization of Monoterpene Epoxides
por: Sánchez-Velandia, Julián E., et al.
Publicado: (2021)

Bis(perfluoropinacolato)silane: A Neutral Silane Lewis Superacid Activates Si−F Bonds
por: Tschernuth, Florian S., et al.
Publicado: (2021)

Radical Group Transfer of Vinyl and Alkynyl Silanes Driven by Photoredox Catalysis
por: Baussière, Floriane, et al.
Publicado: (2023)

Bis(catecholato)silanes: assessing, rationalizing and increasing silicon's Lewis superacidity
por: Hartmann, Deborah, et al.
Publicado: (2019)

The Reactivity of Isomeric Nitrenium Lewis Acids with Phosphines, Carbenes, and Phosphide
por: Zhu, Diya, et al.
Publicado: (2021)

Electrochemical Hydrosilylation of Alkynes
por: Biremond, Tony, et al.
Publicado: (2022)

Effect of vinyl silane modification on thermal and mechanical properties of starch-polyvinyl alcohol blend
por: Gadhave, Ravindra V, et al.
Publicado: (2019)

Bis(pertrifluoromethylcatecholato)silane: Extreme Lewis Acidity Broadens the Catalytic Portfolio of Silicon
por: Thorwart, Thaddäus, et al.
Publicado: (2021)

Proton-Stabilized Photochemically Reversible E/Z Isomerization of Spiropyrans
por: Kortekaas, L., et al.
Publicado: (2018)

Recent advances in photocatalyzed reactions using well-defined copper(I) complexes
por: Zhong, Mingbing, et al.
Publicado: (2020)

Continuous flow synthesis of Celecoxib from 2-bromo-3,3,3-trifluoropropene
por: Ivanova, Maria, et al.
Publicado: (2021)

Continuous Flow Synthesis of Propofol
por: Mougeot, Romain, et al.
Publicado: (2021)

Electrochemical Hydroboration of Alkynes
por: Aelterman, Maude, et al.
Publicado: (2021)

New Insights into Acylhydrazones E/Z Isomerization: An Experimental and Theoretical Approach †
por: Fernández-Palacios, Sara, et al.
Publicado: (2023)

Sequestration of Carbon Dioxide with Frustrated Lewis Pairs Based on N-Heterocycles with Silane/Germane Groups
por: Ferrer, Maxime, et al.
Publicado: (2021)

Overcoming the thermodynamic equilibrium of an isomerization reaction through oxidoreductive reactions for biotransformation
por: Liu, Jing-Jing, et al.
Publicado: (2019)

Thermodynamic properties of some isomeric 5-(nitrophenyl)-furyl-2 derivatives
por: Dibrivnyi, Volodymyr, et al.
Publicado: (2019)

A General Aqueous Silanization Protocol to Introduce Vinyl, Mercapto or Azido Functionalities onto Cellulose Fibers and Nanocelluloses
por: Beaumont, Marco, et al.
Publicado: (2018)

Study on the graft modification mechanism of macroporous silica gel surface based on silane coupling agent vinyl triethoxysilane
por: Wang, Zheng, et al.
Publicado: (2021)

Characterization of Low-Density Polyethylene and LDPE-Based/Ethylene-Vinyl Acetate with Medium Content of Vinyl Acetate
por: Pham, Nga Thi-Hong
Publicado: (2021)

Silicon Tetrakis(trifluoromethanesulfonate): A Simple Neutral Silane Acting as a Soft and Hard Lewis Superacid
por: Hermannsdorfer, André, et al.
Publicado: (2021)

Recent Advances for the Direct Introduction of the CF(2)Me Moiety
por: Carbonnel, Elodie, et al.
Publicado: (2019)

Room temperature stable E,Z-diphosphenes: their isomerization, coordination, and cycloaddition chemistry
por: Lin, Jieli, et al.
Publicado: (2023)

A to Z of thermodynamics
por: Perrot, Pierre
Publicado: (1998)

Whether planar or corrugated graphitic carbon nitride combined with titanium dioxide exhibits better photocatalytic performance?
por: Ha, Nguyen Thi Thu, et al.
Publicado: (2021)

Photoinduced hydrosilylation through hydrogen abstraction: an NMR and computational study of the structural effect of silane
por: Quach, Thi-Hai-Yen, et al.
Publicado: (2022)

PMMA Bone Cements Modified with Silane-Treated and PMMA-Grafted Hydroxyapatite Nanocrystals: Preparation and Characterization
por: Tham, Do Quang, et al.
Publicado: (2021)

Selective E to Z isomerization of 1,3-Dienes Enabled by A Dinuclear Mechanism
por: Kudo, Eiji, et al.
Publicado: (2021)

Stereodynamics of E/Z isomerization in rotaxanes through mechanical shuttling and covalent bond rotation
por: Corra, Stefano, et al.
Publicado: (2021)

Singlet and Triplet Pathways Determine the Thermal Z/E Isomerization of an Arylazopyrazole-Based Photoswitch
por: Singer, Nadja K., et al.
Publicado: (2023)

Synthesizing and Evaluating the Photocatalytic and Antibacterial Ability of TiO(2)/SiO(2) Nanocomposite for Silicate Coating
por: Le, Manh-Cuong, et al.
Publicado: (2021)

A thermodynamic and kinetic study of the antioxidant activity of natural hydroanthraquinones
por: Vo, Quan V., et al.
Publicado: (2020)

Enantioselective Nickel‐Catalyzed Intramolecular Allylic Alkenylations Enabled by Reversible Alkenylnickel E/Z Isomerization
por: Yap, Connor, et al.
Publicado: (2017)

Solvent-controlled E/Z isomerization vs. [2 + 2] photocycloaddition mediated by supramolecular polymerization
por: Dünnebacke, Torsten, et al.
Publicado: (2020)

Thermodynamic Constants for Association of Isomeric Chlorobenzoic and Toluic Acids With 1,3-Diphenyl-guanidine in Benzene
por: Davis, Marion Maclean, et al.
Publicado: (1961)

Mechanism of Spatial and Temporal Control in Precision Cyclic Vinyl Polymer Synthesis by Lewis Pair Polymerization
por: McGraw, Michael L., et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_msvh42p606gs30e76tqmt9eee2