Tuning Deazaflavins Towards Highly Potent Reducing Photocatalysts Guided by Mechanistic Understanding – Enhancement of the Key Step by the Internal Heavy Atom Effect

Deazaflavins are well suited for reductive chemistry acting via a consecutive photo‐induced electron transfer, in which their triplet state and semiquinone – the latter is formed from the former after electron transfer from a sacrificial electron donor – are key intermediates. Guided by mechanistic...

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Detalles Bibliográficos
Autores principales: Pavlovska, Tetiana, Král Lesný, David, Svobodová, Eva, Hoskovcová, Irena, Archipowa, Nataliya, Kutta, Roger Jan, Cibulka, Radek
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541856/
https://www.ncbi.nlm.nih.gov/pubmed/35538649
http://dx.doi.org/10.1002/chem.202200768

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9541856/
https://www.ncbi.nlm.nih.gov/pubmed/35538649
http://dx.doi.org/10.1002/chem.202200768

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