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Dinitrogen Binding at a Trititanium Chloride Complex and Its Conversion to Ammonia under Ambient Conditions
Reaction of [TiCp*Cl(3)] (Cp*=η(5)‐C(5)Me(5)) with one equivalent of magnesium in tetrahydrofuran at room temperature affords the paramagnetic trinuclear complex [{TiCp*(μ‐Cl)}(3)(μ(3)‐Cl)], which reacts with dinitrogen under ambient conditions to give the diamagnetic derivative [{TiCp*(μ‐Cl)}(3)(μ(...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9542190/ https://www.ncbi.nlm.nih.gov/pubmed/35748604 http://dx.doi.org/10.1002/anie.202204544 |