Cargando…

Dinitrogen Binding at a Trititanium Chloride Complex and Its Conversion to Ammonia under Ambient Conditions

Reaction of [TiCp*Cl(3)] (Cp*=η(5)‐C(5)Me(5)) with one equivalent of magnesium in tetrahydrofuran at room temperature affords the paramagnetic trinuclear complex [{TiCp*(μ‐Cl)}(3)(μ(3)‐Cl)], which reacts with dinitrogen under ambient conditions to give the diamagnetic derivative [{TiCp*(μ‐Cl)}(3)(μ(...

Descripción completa

Detalles Bibliográficos
Autores principales:	del Horno, Estefanía, Jover, Jesús, Mena, Miguel, Pérez‐Redondo, Adrián, Yélamos, Carlos
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9542190/ https://www.ncbi.nlm.nih.gov/pubmed/35748604 http://dx.doi.org/10.1002/anie.202204544

Ejemplares similares

Ammonia from dinitrogen at ambient conditions by organometallic catalysts
por: Bora, Debashree, et al.
Publicado: (2022)

Ambient ammonia synthesis via palladium-catalyzed electrohydrogenation of dinitrogen at low overpotential
por: Wang, Jun, et al.
Publicado: (2018)

Facile conversion of ammonia to a nitride in a rhenium system that cleaves dinitrogen
por: Connor, Gannon P., et al.
Publicado: (2022)

Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand
por: Kuriyama, Shogo, et al.
Publicado: (2016)

Nature's nitrite-to-ammonia expressway, with no stop at dinitrogen
por: Kroneck, Peter M. H.
Publicado: (2021)

Dinitrogen cleavage and hydrogenation to ammonia with a uranium complex
por: Xin, Xiaoqing, et al.
Publicado: (2022)

Catalytic Dinitrogen Reduction to Ammonia at a Triamidoamine–Titanium Complex
por: Doyle, Laurence R., et al.
Publicado: (2018)

A Chatt‐Type Catalyst with One Coordination Site for Dinitrogen Reduction to Ammonia
por: Engesser, Tobias A., et al.
Publicado: (2020)

Rhenium‐Mediated Conversion of Dinitrogen and Nitric Oxide to Nitrous Oxide
por: Alig, Lukas, et al.
Publicado: (2021)

Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes
por: McWilliams, Sean F., et al.
Publicado: (2015)

Cation assisted binding and cleavage of dinitrogen by uranium complexes
por: Jori, Nadir, et al.
Publicado: (2022)

Unique behaviour of dinitrogen-bridged dimolybdenum complexes bearing pincer ligand towards catalytic formation of ammonia
por: Tanaka, Hiromasa, et al.
Publicado: (2014)

A model for dinitrogen binding in the E(4) state of nitrogenase
por: Thorhallsson, Albert Th., et al.
Publicado: (2019)

Electrosynthesis of formamide from methanol and ammonia under ambient conditions
por: Meng, Nannan, et al.
Publicado: (2022)

Photoelectrochemical Conversion of Dinitrogen to Benzonitrile: Selectivity Control by Electrophile‐ versus Proton‐Coupled Electron Transfer
por: Fritz, Maximilian, et al.
Publicado: (2022)

Lewis Acid-Induced Dinitrogen Cleavage in an Anionic Side-on End-on Bound Dinitrogen Diniobium Hydride Complex
por: Suzuki, Naofumi, et al.
Publicado: (2022)

Side‐On Bonded Beryllium Dinitrogen Complexes
por: Deng, Guohai, et al.
Publicado: (2020)

Stabilization of the Dinitrogen Analogue, Phosphorus Nitride
por: Martinez, Jorge L., et al.
Publicado: (2020)

Synthesis of pyrimidines from dinitrogen and carbon
por: Shi, Xianghui, et al.
Publicado: (2022)

Ammonia Synthesis at Ambient Conditions via Electrochemical Atomic Hydrogen Permeation
por: Ripepi, Davide, et al.
Publicado: (2021)

Dinitrogen and Related Chemistry of the Lanthanides: A Review of the Reductive Capture of Dinitrogen, As Well As Mono- and Di-aza Containing Ligand Chemistry of Relevance to Known and Postulated Metal Mediated Dinitrogen Derivatives
por: Gardiner, Michael G., et al.
Publicado: (2010)

Electrocatalytic Reduction of Dinitrogen to Ammonia with Water as Proton and Electron Donor Catalyzed by a Combination of a Tri-ironoxotungstate and an Alkali Metal Cation
por: Tzaguy, Avra, et al.
Publicado: (2023)

Dinitrogen fixation in aphotic oxygenated marine environments
por: Rahav, Eyal, et al.
Publicado: (2013)

Coupling Dinitrogen and Hydrocarbons through Aryl Migration
por: McWilliams, Sean F., et al.
Publicado: (2020)

Cyanate Formation via Photolytic Splitting of Dinitrogen
por: Schluschaß, Bastian, et al.
Publicado: (2021)

Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum–dinitrogen complexes: unique behavior of ferrocene moiety as redox active site
por: Kuriyama, Shogo, et al.
Publicado: (2015)

Photocatalytic and electrocatalytic approaches towards atmospheric nitrogen reduction to ammonia under ambient conditions
por: John, Jude, et al.
Publicado: (2019)

Bismuth-Based Free-Standing Electrodes for Ambient-Condition Ammonia Production in Neutral Media
por: Sun, Ying, et al.
Publicado: (2020)

Differential Responses of Dinitrogen Fixation, Diazotrophic Cyanobacteria and Ammonia Oxidation Reveal a Potential Warming-Induced Imbalance of the N-Cycle in Biological Soil Crusts
por: Zhou, Xiaobing, et al.
Publicado: (2016)

Tropical carbon sink accelerated by symbiotic dinitrogen fixation
por: Levy-Varon, Jennifer H., et al.
Publicado: (2019)

CO‐Induced Dinitrogen Fixation and Cleavage Mediated by Boron
por: Deng, Guohai, et al.
Publicado: (2020)

Dinitrogen Fixation: Rationalizing Strategies Utilizing Molecular Complexes
por: Masero, Fabio, et al.
Publicado: (2020)

Dinitrogen cleavage by a dinuclear uranium(iii) complex
por: Jori, Nadir, et al.
Publicado: (2023)

Crystal structure of μ-oxido-1,1′κ(2) O:O-bis{tetra-μ-oxido-1:2κ(2) O:O;1:3κ(2) O:O;2:3κ(4) O:O-tris[1,2,3(η(5))-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}
por: Pérez-Redondo, Adrián, et al.
Publicado: (2015)

Transition Metal Aluminum Boride as a New Candidate for Ambient-Condition Electrochemical Ammonia Synthesis
por: Fu, Yang, et al.
Publicado: (2020)

Numerical Analysis of Urea to Ammonia Conversion in Automotive Selective Catalytic Reduction Realistic Conditions
por: Payri, Raúl, et al.
Publicado: (2021)

(Electro‐)chemical Splitting of Dinitrogen with a Rhenium Pincer Complex
por: van Alten, Richt S., et al.
Publicado: (2020)

Selectivity of tungsten mediated dinitrogen splitting vs. proton reduction
por: Schluschaß, Bastian, et al.
Publicado: (2019)

Silylamido supported dinitrogen heterobimetallic complexes: syntheses and their catalytic ability
por: Zhai, Dan-dan, et al.
Publicado: (2020)

Molecular Electrochemical Reductive Splitting of Dinitrogen with a Molybdenum Complex
por: Merakeb, Lydia, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_f66bj47u98j1v2rbp08p97u28k