Ligand‐Enabled Disproportionation of 1,2‐Diphenylhydrazine at a P(V)‐Center

We present herein the synthesis of a nearly square‐pyramidal chlorophosphorane supported by the tetradentate bis(amidophenolate) ligand, N,N′‐bis(3,5‐di‐tert‐butyl‐2‐phenoxy)‐1,2‐phenylenediamide. After chloride abstraction the resulting phosphonium cation efficiently promotes the disproportionation...

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Detalles Bibliográficos
Autores principales: Karnbrock, Simon B. H., Golz, Christopher, Mata, Ricardo A., Alcarazo, Manuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9542402/
https://www.ncbi.nlm.nih.gov/pubmed/35714171
http://dx.doi.org/10.1002/anie.202207450

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9542402/
https://www.ncbi.nlm.nih.gov/pubmed/35714171
http://dx.doi.org/10.1002/anie.202207450

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