Cargando…

Mechanistic and Kinetic Investigations of ON/OFF (Photo)Switchable Binding of Carbon Monoxide by Chromium(0), Molybdenum(0) and Tungsten(0) Carbonyl Complexes with a Pyridyl‐Mesoionic Carbene Ligand

This work tackles the photochemistry of a series of mononuclear Cr(0), Mo(0) and W(0) carbonyl complexes containing a bidentate mesoionic carbene ligand of the 1,2,3‐triazol‐5‐ylidene type. FTIR spectroscopy, combined with density functional theory calculations, revealed a clean photo‐induced reacti...

Descripción completa

Detalles Bibliográficos
Autores principales: Boden, Pit J., Di Martino‐Fumo, Patrick, Bens, Tobias, Steiger, Sophie T., Marhöfer, Daniel, Niedner‐Schatteburg, Gereon, Sarkar, Biprajit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9542575/
https://www.ncbi.nlm.nih.gov/pubmed/35705508
http://dx.doi.org/10.1002/chem.202201038